AN EFFICIENT TiO2-SUPPORTED RUTHENIUM (Ru/TiO2) CATALYST FOR ELECTROCHEMICAL HYDROGEN GENERATION FROM AQUEOUS POTASSIUM BOROHYDRIDE

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Tarih

2020

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Inst Materials Physics

Erişim Hakkı

info:eu-repo/semantics/closedAccess

Özet

In this study, a TiO2-supported ruthenium catalyst (denoted as Ru/TiO2) was facilely synthesized by chemical reduction method without the use of any chemical reducing reagents. Using a 2 wt.% KBH4 + 1 wt.% KOH solution, hydrogen generation rate was as high as 137423.9 mL* min(-1) g(-1) at 30 C-0, and apparent activation energy was calculated as 55.48 kJ*mol(-1). Compared with similar Ru-based catalysts reported in literature, the Ru/TiO2 catalyst synthesized by chemical reduction method in this study indicates higher catalytic activity and lower apparent activation energy.

Açıklama

Anahtar Kelimeler

Characterization, Efficient catalyst, Hydrogen generation, Hydrolysis, Kinetics, Potassium borohydride, TiO2, synthesis

Kaynak

Digest Journal of Nanomaterials and Biostructures

WoS Q Değeri

Q4

Scopus Q Değeri

Cilt

15

Sayı

2

Künye