Synthesis and characterization of a new di-functional ligand and its metal complexes: an experimental, theoretical, cyclic voltammetric and antimicrobial study.
Yükleniyor...
Dosyalar
Tarih
2015
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Synthesis and Reactivity in Inorganic, Metal-Organic & Nano Metal Chemistry
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A new difunctional Schiff base ligand and its some metal complexes were synthesized. The compounds were characterized by elemental analysis, 1H-NMR, 13C-NMR, FT-IR, UV-VIS, magnetic susceptibility measurements, molar conductivity measurements, and thermal gravimetric analysis techniques. Additionally, DPPH scavenging, metal chelating and antibacterial activity of compounds were examined via in vitro methods. The lowest DPPH scavenging activity observed by Co(II) as 36.28% and highest was ligand as 52.00%. A cyclic voltammetric study was also carried out to determine redox potentials of the compounds. Some theoretical studies such as 1H-NMR, HOMO-LUMO, and mapped electron density of the ligand were also carried out successfully.
Açıklama
Anahtar Kelimeler
Schiff base complexes, cyclic voltammetry, antimicrobial, antioxidant, Gaussian 09, electron density
Kaynak
Synthesis and Reactivity in Inorganic, Metal-Organic & Nano Metal Chemistry
WoS Q Değeri
Scopus Q Değeri
Cilt
45
Sayı
Künye
Baykara, H., Ilhan, S., Oztomsuk, A., Seyitoglu, M. S., Levent, A., Okumus, V., & Dündar, A. (2015). Synthesis and characterization of a new difunctional ligand and its metal complexes: an experimental, theoretical, cyclic voltammetric, and antimicrobial study. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 45(12), 1795-1807.