Synthesis and characterization of 1,2-bis(2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy)ethane ant its metal complexes:An experimental, theoretical, electrochemical, antioxidant and antibacterial study
Yükleniyor...
Dosyalar
Tarih
2014
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
A new Schiff base ligand was synthesized by reaction of 5-bromosalicylaldehyde with 1,2-bis(4-chloro-2- aminophenoxy)ethane. Then the Schiff base complexes were synthesized by the reaction of metal salts and the novel Schiff base. The molar conductivity properties of the complexes were studied and found out that the complexes are nonelectrolytes. The structures of the ligand and its metal complexes were characterized by elemental analysis, FT-IR, UV–VIS, magnetic susceptibility measurements, molar conductivity measurements, and thermal gravimetric analysis. In addition antioxidant, theoretical NMR studies and cyclic voltammetry of the complexes were done. Two methods namely metal chelating activity and diphenylpicrylhydrazyl (DPPH) radical scavenging method were used to determine the antioxidant activity, and antibacterial properties of the compounds were also studied.
Açıklama
Anahtar Kelimeler
Schiff base complexes, Cyclic voltammetry, Antioxidant, Gaussian, DFT, HF
Kaynak
Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy
WoS Q Değeri
Scopus Q Değeri
Cilt
118
Sayı
Künye
Ilhan, S., Baykara, H., Oztomsuk, A., Okumus, V., Levent, A., Seyitoglu, M. S., & Ozdemir, S. (2014). Synthesis and characterization of 1, 2-bis (2-(5-bromo-2-hydroxybenzilidenamino)-4-chlorophenoxy) ethane and its metal complexes: An experimental, theoretical, electrochemical, antioxidant and antibacterial study. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 118, 632-642.
