Influence of plasma treatment on electrochemical activity of Ni (o)-based catalyst for hydrogen production by hydrolysis of NaBH 4
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Tarih
2013-10-15
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Journal of Power Sources
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
n this study, the hydrogen generation from the hydrolysis of NaBH4 with Ni (o) catalyst prepared in the presence of plasma is investigated. The catalytic properties of nickel catalyst prepared in the presence of plasma are investigated based on NaBH4 concentration, NaOH concentration, temperature, plasma applying time and plasma applying voltage. The results indicated that nickel catalyst reduced with plasma was completed in only 35 min, while the nickel catalyst produced in known method is completed in 80 min. Characteristics of this nickel-based catalyst are carried out by using XRD, BET, SEM and XPS. The activation energy for zero-order is found to be 51.35 kJ mol-1.
Açıklama
Anahtar Kelimeler
Plasma; Sodium borohydride; Nickel catalyst; Hydrolysis; Hydrogen generation
Kaynak
WoS Q Değeri
Scopus Q Değeri
Cilt
Sayı
Künye
22
