Novel cobalt (II), zinc (II) phthalocyanines bearing discrete substituents: Synthesis, characterization, aggregation behavior, electrochemical properties and antioxidant activity

Basit Öğe Kaydı
dc.authoridhttps://orcid.org/0000-0002-5505-2700en_US
dc.contributor.authorAğırtaş, Salih
dc.contributor.authorCabir, Beyza
dc.contributor.authorDündar, Abdurrahman
dc.contributor.authorOkumuş, Veysi
dc.contributor.authorCeyhan, Gökhan
dc.date.accessioned2019-12-25T11:31:00Z
dc.date.available2019-12-25T11:31:00Z
dc.date.issued2014en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstractA new phthalonitrile derivative bearing 3,4,5-trimethoxybenzyloxy and chloro-substituents at peripheral position was prepared by a nucleophilic displacement reaction. Cyclotetramerization of phthalonitrile derivative in dimethylsulfoxide (DMSO) gave the metallophthalocyanines. Novel Co(II), Zn(II) phthalocyanines (Pcs) were obtained from the reaction 4-[(3,4,5- trimethoxybenzyloxy]-5-chlorophthalonitrile and metal salts. The novel compounds have been characterized by using elemental analysis, UV-Vis, FTIR, 1H-NMR spectral data. The aggregation behaviors of Co(II), Zn(II) Pcs were also investigated. These metallophthalocyanines do not show any aggregation behavior between 1.2 × 10−5 and 4.0 × 10−6Mconcentration range in DMF. The antioxidant activities of Pcs were investigated antioxidant assays such as free radical scavenging ability of 1,1-diphenyl-2-picryl-hydrazyl (DPPH) and ferrous ion chelating ability. Furthermore, the redox properties of the Pcs complexes were investigated by using cyclic voltammetry.en_US
dc.description.provenanceSubmitted by Veysi OKUMUŞ (veysiokumus@siirt.edu.tr) on 2019-12-23T17:26:59Z No. of bitstreams: 1 A17.pdf: 709494 bytes, checksum: d8e0f1f1f753a4d3118a170b0b00fbd0 (MD5)en
dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-25T11:31:00Z (GMT) No. of bitstreams: 1 A17.pdf: 709494 bytes, checksum: d8e0f1f1f753a4d3118a170b0b00fbd0 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-25T11:31:00Z (GMT). No. of bitstreams: 1 A17.pdf: 709494 bytes, checksum: d8e0f1f1f753a4d3118a170b0b00fbd0 (MD5) Previous issue date: 2014en
dc.identifier.citationAğırtaş, M. S., Cabir, B., Dundar, A., Okumus, V., & Ceyhan, G. (2014). Novel Cobalt (II), Zinc (II) Phthalocyanines Bearing Discrete Substituents: Synthesis, Characterization, Aggregation Behavior, Electrochemical Properties, and Antioxidant Activity. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry, 44(8), 1092-1098.en_US
dc.identifier.endpage1098en_US
dc.identifier.issue8en_US
dc.identifier.startpage1092en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2422
dc.identifier.volume44en_US
dc.institutionauthorOkumuş, Veysi
dc.language.isoenen_US
dc.publisherSynthesis and Reactivity in Inorganic, Metal-Organic & Nano Metal Chemistryen_US
dc.relation.ispartofSynthesis and Reactivity in Inorganic, Metal-Organic & Nano Metal Chemistry
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz#KayıtKontrol#
dc.subjectaggregationen_US
dc.subjectantioxidanten_US
dc.subjectchelating activityen_US
dc.subjectelectrochemical propertiesen_US
dc.subjectphthalocyaninesen_US
dc.subjectsynthesisen_US
dc.titleNovel cobalt (II), zinc (II) phthalocyanines bearing discrete substituents: Synthesis, characterization, aggregation behavior, electrochemical properties and antioxidant activityen_US
dc.typeArticleen_US

Dosyalar

Orijinal paket
Listeleniyor 1 - 1 / 1
Küçük Resim
İsim:
A17.pdf
Boyut:
692.87 KB
Biçim:
Adobe Portable Document Format
Açıklama:
Makale
İndir
Lisans paketi
Listeleniyor 1 - 1 / 1
[ X ]
İsim:
license.txt
Boyut:
1.44 KB
Biçim:
Item-specific license agreed upon to submission
Açıklama:
İndir

Koleksiyon

2) Makale