New water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties.

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dc.authoridhttps://orcid.org/0000-0002-5505-2700en_US
dc.contributor.authorAğırtaş, Salih
dc.contributor.authorÇelebi, Metin
dc.contributor.authorGümüş, Selçuk
dc.contributor.authorÖzdemir, Sadin
dc.contributor.authorOkumuş, Veysi
dc.date.accessioned2019-12-25T11:46:42Z
dc.date.available2019-12-25T11:46:42Z
dc.date.issued2013en_US
dc.departmentFen - Edebiyat Fakültesien_US
dc.description.abstractNovel substituted phthalonitrile derivatives were obtained by the reaction of 2-(4-hydroxyphenylazo) benzoic acid and 4,5-dichloro-1,2-dicyanobenzene, or 4-nitrophthalonitrile. Peripherally phenoxy phenyl diazenyl benzoic acid substituted zinc (II) phthalocyanine complexes, and their sodium salts were synthesized and characterized for the first time. The newly synthesized phthalocyanine complexes show excellent solubility in water. The aggregation investigations carried out in different concentrations indicate that phenoxy phenyl diazenyl benzoic acid-substituted phthalocyanine compounds do not have any aggregation behavior for the concentration range of 7.00 _ 10_5e4.38 _ 10_6 M in DMF. The antioxidant activities of DMF solution of compounds were analyzed through radical scavenging, and chelating ability to Fe2ş cation. Additionally, new compounds did not show any antibacterial activity against some selected bacteria cultures. Moreover, the ground-state geometries of the complexes were optimized using density functional theory (DFT) methods at B3LYP/6-31G(d,p) level in order to obtain information about the 3D geometries and electronic structure.en_US
dc.description.provenanceSubmitted by Veysi OKUMUŞ (veysiokumus@siirt.edu.tr) on 2019-12-23T18:19:26Z No. of bitstreams: 1 A11.pdf: 1374278 bytes, checksum: 595e05b84e38be826f33dfc4488db7d9 (MD5)en
dc.description.provenanceApproved for entry into archive by Esra Diriarın (esradiriarin@siirt.edu.tr) on 2019-12-25T11:46:42Z (GMT) No. of bitstreams: 1 A11.pdf: 1374278 bytes, checksum: 595e05b84e38be826f33dfc4488db7d9 (MD5)en
dc.description.provenanceMade available in DSpace on 2019-12-25T11:46:42Z (GMT). No. of bitstreams: 1 A11.pdf: 1374278 bytes, checksum: 595e05b84e38be826f33dfc4488db7d9 (MD5) Previous issue date: 2013en
dc.identifier.citationAğırtaş, M. S., Çelebi, M., Gümüş, S., Özdemir, S., & Okumuş, V. (2013). New water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties. Dyes and Pigments, 99(2), 423-431.en_US
dc.identifier.endpage431en_US
dc.identifier.startpage423en_US
dc.identifier.urihttps://hdl.handle.net/20.500.12604/2428
dc.identifier.volume99en_US
dc.institutionauthorOkumuş, Veysi
dc.language.isoenen_US
dc.publisherDyes and Pigmentsen_US
dc.relation.ispartofDyes and Pigments
dc.relation.publicationcategoryMakale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmz#KayıtKontrol#
dc.subjectPhthalocyaninesen_US
dc.subjectPhthalonitrile derivativesen_US
dc.subjectAntioxidant activitiesen_US
dc.subjectAggregation Solubilityen_US
dc.subjectDFTen_US
dc.titleNew water soluble phenoxy phenyl diazenyl benzoic acid substituted phthalocyanine derivatives: Synthesis, antioxidant activities, atypical aggregation behavior and electronic properties.en_US
dc.typeArticleen_US

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