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Öğe Family stress and resilience to earthquake-related economic hardship in Turkish families with preschool children.(American Psychological Association (APA), 2025-05-29) Jan Höltge; Nilüfer Kuru; Michael UngarLife-threatening earthquakes can lead to immediate and prolonged economic hardship that challenges the lives of the survivors. We know little about (a) how these economic risks impact families with preschool children, that is, the health of parents, the behavior of their children, and their relationships, and (b) the necessary family resources that support them. We utilized the Family Stress Model and multisystemic resilience theory to examine the effects of economic hardship on families with preschoolers who recently experienced an earthquake, focusing on ways to enhance their resilience. This study used an exploratory, data-driven statistical approach to analyze cross-sectional data from 377 families (children's age range = 4-6) that experienced the Kahramanmara & scedil; earthquake in T & uuml;rkiye in February 2024. Economic risk showed a direct relationship with problematic child behavior, which was associated with parental depression and the child-parent relationship, which provides additional perspectives on the Family Stress Model. Higher levels of economic hardship were associated with significantly lower levels of most family resources, with meaning making following adversity acting as a mediator for these effects. A combination of family communication, problem solving, and social and economic resources was identified as important for all family members, while lower levels of family spirituality were additionally important for children's resilience. Because most family resources were directly associated with parental depression, interventions should prioritize supporting parents so they can, in turn, better care for their young children. Future research utilizing the Family Stress Model should examine potential bidirectional effects between parental health and child behavior, particularly in disaster contexts.Öğe Epoxidation of cyclooctene and 1,5-cyclooctadiene by sodium perborate oxidation(ACG Publications, 2009) Güneş, Yakup; Şenocak, Erdal; Tosun, Cemal; Taşkesenligil, YavuzSodium perborate oxidizes cyclooctene and 1,5-Cyclooctadiene to form the corresponding epoxides in good yields under mild conditionsÖğe Enantioselective synthesis of cyclic, quaternary oxonitriles(American Chemical Society, 2010) Güneş, Yakup; Polat, Muhammed Fatih; Şahin, Ertan; Fleming, Fraser F.; Altundaş, RamazanQuaternary oxonitriles are stereoselectively generated from the union of five-, six-, and seven-membered 2-chloroalkenecarbonitriles with chiral alcohols via a Claisen rearrangement. The strategy rests on a new conjugate addition-elimination of allylic alkoxides to 2-chlorocycloalkenecarbonitriles to afford substituted 2-alkoxyalkenenitriles. Subsequent thermolysis unmasks a cyclic oxonitrile while selectively forming a new quaternary center with enantiomeric ratios typically greater than 9:1. The overall alkylation strategy addresses the challenge of enantioselectively generating hindered, quaternary centers while simultaneously installing ketone, nitrile, and olefin functionalities.Öğe Enantioselective installation of quaternary centers in cyclic oxonitriles(Wiley-VCH Verlag, 2015) Güneş, Yakup; Arçelik, Nejat; Şahin, Ertan; Fleming, Fraser F.; Altundaş, RamazanQuaternary centers are rapidly and selectively installed in a series of seven-membered and bridged cyclic oxonitriles through conjugate addition of an alkoxide to chloroalkenenitriles, followed by a Claisen rearrangement. Using this strategy, the stereogenic information of the carbinol in secondary allylic alcohols is transferred to the newly generated quaternary center. Experimentally, the sequence rapidly gives alkyl cyanocycloheptanones and bicycloalkanonecarbonitriles in good yield and with high selectivity, in a single synthetic operation.Öğe Hıdır b. Abdirrahman el-Ezdî ve et-Tibyân fî tefsîri’l-Kur’ân Adlı Tefsirinin Tanıtım ve Tahlili(Bingöl Üniversitesi İlahiyat Fakültesi Dergisi, 2018-12-30) Özcan, Esat; Aydar, HidayetTefsir, Allah Teâlâ’nın kelamı olan Kur’ân’ı açıklama ve yorumlama faaliyetidir. Tefsir faaliyetleri, Hz. Peygamber’le başlamış, ondan sonra sahabe, tâbiîn ve diğer alimler tarafından sürdürülmüş ve bu konuda yüzlerce eser meydana getirilmiştir. Bu eserlerin bir kısmı, Kur’ân’ın sadece bir bölümünü ihtiva ederken bir kısmı da Kur’ân’ın tamamını ele almıştır. Aynı şekilde bu çalışmaların bir kısmı kısa ve özet olurken bir kısmı da uzun ve ayrıntılı olmuştur. Tefsir faaliyeti, ya Hz. Peygamber, sahabe, tâbiîn, diğer alimlerin görüşleri ile İsrâiliyât denilen ve Ehl-i Kitap’tan yapılan nakillerle ya da değişik ilimlerin verileri vasıtasıyla yapılmaktadır. Bu iki yöntemi kullanarak bir tefsir meydana getiren alimlerden birisi de hicri 700, miladi 1301 yılında, Dımaşk’ta vefat eden Hıdır b. Abdirrahman el-Ezdî’dir. Ezdî, et-Tibyân fî tefsîri’l-Kur’ân olarak isimlendirdiği tefsirinde Kur’ân’ı baştan sona kadar ele almakta; ancak sadece tefsire ihtiyaç duyduğunu düşündüğü kelime ve ayetleri tefsir ederek kısa ama özlü bir tefsir ortaya koymaktadır. Müfessir, tefsirinde kendisinden önce yazılmış olan tefsirlerin bir özetini ortaya koymaktadır.
