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Öğe Anaerobic co-digestion of oil-extracted spent coffee grounds with various wastes: Experimental and kinetic modeling studies(Elsevier Sci Ltd, 2021) Atelge, M. R.; Atabani, A. E.; Abut, Serdar; Kaya, M.; Eskicioglu, Cigdem; Semaan, Georgeio; Lee, ChangsooThe effect of oil extraction from spent coffee grounds as a pre-treatment strategy prior to anaerobic digestion besides assessing the feasibility of defatted spent coffee grounds co-digestion with spent tea waste, glycerin, and macroalgae were examined. Mesophilic BMP tests were performed using defatted spent coffee grounds alongside four co-substrates in the ratio of 25, 50, and 75%, respectively. The highest methane yield was obtained with the mono-digestion of defatted spent coffee grounds with 336 +/- 7 mL CH4/g VS and the yield increased with the increase in the mass ratio of defatted spent coffee grounds during co-digestion. Moreover, defatted spent coffee grounds showed the highest VS and TS removal at 35.5% and 32.1%, respectively and decreased thereafter. Finally, a linear regression model for the interaction effects between substrates was demonstrated and showed that distinctly mixing defatted spent coffee grounds, spent coffee grounds, and spent tea waste outperforms other triple mixed substrates.Öğe Spent coffee grounds anaerobic digestion: Investigating substrate to inoculum ratio and dilute acid thermal pretreatment(Elsevier Sci Ltd, 2023) Semaan, Georgeio; Atelge, M. R.; Cayetano, Roent Dune; Kumar, Gopalakrishnan; Kommedal, RoaldSpent coffee grounds have the potential of being used in further bioprocesses to produce materials and fuels. In Norway, the relative abundance and ease of collection of this waste substrate make it a candidate for investi-gation. For this study, the substrate-to-inoculum ratio as well as a combined dilute acid-thermal pretreatment were assessed by a series of biochemical methane potential assays using spent coffee grounds as a substrate. Reactors with substrate-to-inoculum ratio 2 demonstrated a relatively low hydrolysis rate constant (kh) and comparatively high volatile fatty acids/alkalinity concentrations rendering them inapt to produce bio-CH4. Pretreatment was conducted over varying contact times (15-45 min), dilute acid concentrations (1.5-2.5 %, v/ v), and liquid-to-solid ratios (10-20 %, v/w) and evaluated using response surface methodology. To determine bio-CH4 yield, pretreatment time and the interaction between acid concentration and liquid-to-solid ratio are considered significant variables, suggesting a shared importance. Chemical oxygen demandremoval is primarily contingent upon changes in liquid-to-solid ratio. Finally, Fourier-transform infrared spectroscopy of the dis-carded solid phase showed that the major functional groups are still widely present in the coffee grounds even after pretreatment was applied. A better understanding of the biodegradability profile of spent coffee grounds as a function of substrate-to-inoculum ratio is achieved.