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    Reactive Blue 19 Adsorption on Activated Carbon from Pumpkin (Cucurbita Pepo) Seed Waste: Kinetic, Isotherm and Thermodynamic Studies
    (Kauno Technologijos Universitetas, 2024) Kızıl, Yusuf; Benek, Veysel; Teğin, İbrahim; Önal, Yunus; Erol, Kadir; Alacabey, İhsan
    In this study, the removal of reactive blue 19 dyestuffs in aqueous systems was investigated by the adsorption method using activated carbon obtained from pumpkin seed waste. Activated carbon obtained from pumpkin seed waste functionalized with ZnCl2 was used as an absorbent. Pumpkin seed hydrochar was characterized by FT-IR, SEM, TGA-DTA, BET, and XPS. In the experimental stages, the adsorption equilibrium time was determined as 45 minutes, the adsorbent dosage was 0.8 g and the optimum pH was 6.0. After this step, the adsorption parameters of Langmuir, Freundlich, Temkin, and Dubinin-Radushkevich isotherms were investigated. It has been pointed out that the adsorption process fits better with the Freundlich isotherm model, and the adhesion occurs in a multilayered manner and on a heterogeneous surface. Freundlich and Dubinin-Radushkevich isotherms support that the bonding mechanism is realized by physical interactions. When the kinetic data were evaluated, adsorption mechanism was found to be compatible with the pseudo-second-order kinetic model. The thermodynamic parameters of adsorption indicate that the system is endothermic, and the adsorption of reactive blue 19 on activated carbon is a spontaneous process. © 2024, Kauno Technologijos Universitetas. All rights reserved.
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    Öğe
    Using Natural Stone Pumice in Van Region on Adsorption of Some Textile Dyes
    (Journal of The Turkish Chemical Society, 2017) Kul, Ali Rıza; Benek, Veysel; Selçuk, Ahmet; Onursal, Nilgün
    Toxic effect of textile dyes their increasing quantities in air, soil and water environments, because of growing of industrial activities, they must be taken into consideration since they give harm to the environment. We come across textile dyes in natural wetlands as result of uncontrolled industrial wastes. Textile dyes that can accumulate easily in their environments may show toxic effects. Pumice, accruing as a result of volcanic events and durable against chemical factors, is a rock that has porous structure. Pumices have a porous structure because of sudden cooling of the rock and sudden leaving of gases a result of volcanic events. Thanks to these pores, pumices’ heat and sound insulation are quite high. The most distinctive feature of pumice from other rocks is that it has different colors and there is not crystal water in its porous structure. Adsorption studies are applied with Van Pumice at pH = 6, the adsorption mechanism and changing dye concentration. As result of these researches, it has been found out that there are different adsorption movements at pH 6 between Neutral Red and Van Pumice. The result of this study shows that the Pumice found in Lake Van gives a better fit for the Langmuir Isotherm (model) and the amount of adsorption increases with the temperature. We thereby conclude that the Pumice located in Lake Van is a recommended adsorbent for filtering the used textile dye in aqueous medium.