Asymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexes

Durap, FeyyazKarakas, Duygu ElmaAk, BunyaminBaysal, AkinAydemir, Murat2024-12-242024-12-2420160022-328X1872-8561https://doi.org/10.1016/j.jorganchem.2016.05.025https://hdl.handle.net/20.500.12604/6635Known Ru(II), Rh(I) and Ir(III) complexes of C-2-symmetric ferrocenyl based chiral bis(phoshinite) ligands were catalyzed the asymmetric transfer hydrogenation of alkyl/aryl or alkyl methyl ketones. Corresponding secondary alcohols were obtained with high enantioselectivities up to 98% ee and reactivities using iso-propanol as the hydrogen source. (C) 2016 Elsevier B.V. All rights reserved.eninfo:eu-repo/semantics/closedAccessTransfer hydrogenationC-2-symmetryFerrocenyl ligandsPhosphiniteAsymmetric transfer hydrogenation of alkyl/aryl or alkyl/methyl ketones catalyzed by known C2-symmetric ferrocenyl-based chiral bis(phosphinite)-Ru(II), Rh(I) and Ir(III) complexesArticle8189297Q2WOS:000380751600013Q22-s2.0-8497460363510.1016/j.jorganchem.2016.05.025