Synthesis and characterization of a triphenylamine-dibenzosuberenone-based conjugated organic material and an investigation of its photovoltaic properties

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Tarih

2021

Dergi Başlığı

Dergi ISSN

Cilt Başlığı

Yayıncı

Sage Publications Ltd

Erişim Hakkı

info:eu-repo/semantics/openAccess

Özet

3,7-Bis[4-(diphenylamino)phenyl]-5H-dibenzo[a,d][7]annulen-5-one, containing triphenylamine- and dibenzosuberenone-based donor-acceptor-donor (D-A-D) conjugated moieties, is synthesized in high yield by Suzuki coupling of 5H-dibenzo[a,d][7]annulen-5-one with [4-(diphenylamino)phenyl]boronic acid. The most important part of the present study is the creation of a dye-sensitized solar cell structure using the synthesized organic molecule for the first time and the power conversion efficiency of this structure. Three solar cell devices are prepared and are named as first device, second device, and third device. The power conversion efficiency (%) value for first device, second device, and third device is calculated as 2.54, 2.38, and 2.54, respectively. Moreover, the chemical structure of the synthesized compound is determined by nuclear magnetic resonance, infrared, ultraviolet visible, fluorescence spectroscopy, and high-resolution mass spectrometry.

Açıklama

Anahtar Kelimeler

characterization, dibenzosuberenone, D-A-D, D-pi-A, photovoltaic, synthesis, triphenylamine

Kaynak

Journal of Chemical Research

WoS Q Değeri

Q4

Scopus Q Değeri

Q3

Cilt

45

Sayı

1-2

Künye