Hydrogen Production by Catalytic Hydrolysis of Sodium Borohydride with a Bimetallic Solid-State Co-Fe Complex Catalyst
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Tarih
2015
Yazarlar
Dergi Başlığı
Dergi ISSN
Cilt Başlığı
Yayıncı
Taylor Francis-Separation Science and Technology
Erişim Hakkı
info:eu-repo/semantics/openAccess
Özet
The addition of the active non-noble metal species on a ligand can influence the catalytic performance of catalyst. In the present work, a new bi-metallic solid-state complex catalyst system, including 4-4’-methylene bis(2,6-diethyl) aniline-3,5-di-tert-butylsalisilaldimin ligand and Fe and Co metal salts are prepared for hydrogen generation by catalytic hydrolysis of NaBH4. It was found that the Co/Fe mixture ratio, temperature, NaBH4, and NaOH concentrations, all exert considerable influence on the catalytic effectiveness of Co–Fe complex catalyst towards the hydrolysis reaction of NaBH4. The results suggested that the optimal mixture percentage of Co–Fe complex catalyst is 80:20. The obtained complex catalysts are characterized by XRD, FT-IR, and SEM techniques.
Açıklama
Anahtar Kelimeler
Kaynak
WoS Q Değeri
Q3
Scopus Q Değeri
Q2
